PUBLICATIONS
2024
(97) Electrocatalytic Ammonia Oxidation by Pyridyl Substituted Ferrocenes
Ahmed, M. E.; Staples, R. J.; Cundari, T. R.; Warren, T. H.*
ChemRxiv doi: 10.26434/chemrxiv-2024-29hgx
(96) Copper Catalyzed C(sp3)-H α-Acetylation: Generation of Quaternary Centers
Okoromoba, O.; Chen, T.-A.; Jang, E. S.; McMullin, C. L.; Cundari, T. R.*; Warren, T. H.*
Angew. Chem. Int. Ed. doi: 10.1002/anie.202418692
(95) Copper Catalyzed Benzylic sp3 C-H Alkenylation
Chen, T.-A.; Staples, R. J.; Warren, T. H.*
Chem. Sci. 2024, 15, 17685-17690.
(94) Abiotic anammox by a naturally occurring mineral
Chaudhuri, S. R.; Warren, T. H.*
Nature Chemistry 2024, 16, 1574-1575. (News and Views)
(93) Get to Know NO
Ghosh, P.*; Warren, T. H.*
Nature Chemistry 2024, 16, 1382. (In Your Element)
2023
(92) Chemical and Electrocatalytic Ammonia Oxidation by Ferrocenium
Borougeni, M. R.; Greene, C.; Bertke, J. A.; Cundari, T. R.; Warren, T. H.*
ChemRxiv doi: 10.26434/chemrxiv-2023-l1dtg-v2
(91) Thiol and H2S-Mediated NO Generation from Nitrate at Copper(II)
Ghosh, P.*; Stauffer, M.; Ahmed, M. E.; Bertke, J. A.; Staples, R. J.; Warren, T. H.*
J. Am. Chem. Soc. 2023, 145, 12007–12012.
2022
(90) Electrocatalytic Ammonia Oxidation by a Low-Coordinate Copper Complex
Ahmed, M. E.; Borougeni, M. R.; Ghosh, P.; Greene, C.; Kundu, S.; Bertke, J. A.; Warren, T. H.*
J. Am. Chem. Soc. 2022, 144, 21136–21145.
(89) Copper Catalyzed C(sp3)-H Methylation via Radical Relay
Figula, B. C.; Chen, T.-A.; Bertke, J. A.; Warren, T. H.*
ACS Catal. 2022, 12, 11854-11859.
Hosseininasab, V.; DiMucci, I. M.; Ghosh, P.; Bertke, J. A.; Chandrasekharan, S.; Titus, C. J.; Nordlund, D.; Freed. J. H.; Lancaster, K. M.*; Warren, T. H.*
Nature Chemistry 2022, 14, 1265-1269.
(87) NO Coupling at Copper to cis-Hyponitrite: N2O Formation via Protonation and H-Atom Transfer
Ghosh, P.; Stauffer, M.; Hosseininasab, V.; Kundu, S.; Bertke, J. A.; Cundari, T. R.; Warren, T. H.*
J. Am. Chem. Soc. 2022, 144, 15093–15099.
2021
(86) Copper(II) ketimides in sp3 C–H amination
Jayasooriya, I. U.; Bakhoda, A.; Palmer, R.; Ng, K.; Khachemoune, N. L.; Bertke, J. A.; Warren, T. H.*
Chem. Sci. 2021, 12, 15733-15738.
(85) Uncovering Redox Non-innocent Hydrogen-Bonding in Cu(I)-Diazene Complexes
Gardner, E. J.; Marguet, S. C.; Cobb, C. R.; Pham, D. M.; Beringer, J. A. M.; Bertke, J. A.; Shafaat, H.S.*; Warren, T. H.*
J. Am. Chem. Soc. 2021, 143, 15960−15974.
(84) Thionitrite and Perthionitrite in NO Signaling at Zinc
Hosseininasab, V.; Bertke, J. A.; Warren, T. H.* Angew. Chem. Int. Ed. 2021, 60, 21184–21188.
Noted as a Very Important Paper. Highlighted on Science X and other media outlets.
(83) Mechanism of O‐Atom Transfer from Nitrite: Nitric Oxide Release at Copper(II)
Stauffer, M.; Sakhaei, Z.; Greene, C.; Ghosh, P.; Bertke, J. A.; Warren, T. H.*
Inorg. Chem. 2021, 60, 15968-15974. Forum Article in Issue "Renaissance in NO Chemistry"
(82) Quantification of Ni-N-O Bond Angles and NO Activation by X-ray Emission Spectroscopy
Phu, P. N.; Gutierrez, C. E.; Kundu, S.; Sokaras, D.; Kroll, T.; Warren, T. H.*; Stieber, S. C. E.*
Inorg. Chem. 2021, 60, 736-744.
2020
Bakhoda, A.; Okoromoba, O.; Greene, C.; Borougeni, M. R.; Bertke, J. A.; Warren, T.H.*
J. Am. Chem. Soc. 2020, 142, 18483-18490.
(80) Decomposition of Vanadium(V) Alkylidenes Relevant to Olefin Metathesis
Farrell, W.S.*, Greene, C.; Ghosh, P.; Warren, T. H.; Zavalij, P. Y.
Organometallics 2020, 39, 3906-3917.
(79) Radical Capture at Nickel(II) Complexes: C–C, C–N, and C–O Bond Formation
Bakhoda, A.; Wiese, S.; Greene, C.; Figula, B. C.; Bertke, J. A.; Warren, T.H.*
Organometalics 2020, 39, 1710-1718.
(78) Decarboxylative C(sp(3))-S Coupling via Cu-Photoredox Catalysis
Bakhoda, A.; Warren, T. H. Chem 2020, 6, 1048-1050. Chem Preview synopsis
(77) Lewis Acid Coordination Redirects S-Nitrosothiol Signaling Output
Hosseininasab, V.; McQuilken, A. C.; Bakhoda, A.; Bertke, J. A.; Timerghazin, Q. K.*; Warren, T. H.*
Angew. Chem. Int. Ed. 2020, 59, 10854-10858. Noted as a Very Important Paper
2019
(76) Tris(pyrazolyl)borate Copper Hydroxide Complexes Featuring Tunable Intramolecular H-bonding
Gardner, E. J.; Cobb, C. R.; Bertke, J. A.; Warren, T. H.*
Inorg. Chem. 2019, 58, 11248-11255.
(75) Copper-Catalyzed C(sp3)-H Amidation: Sterically Driven Primary and Secondary C-H Site-Selectivity
Bakhoda, A.; Jiang, Q.; Bertke, J. A.; Cundari, T. R.*; Warren, T. H.*
Angew. Chem. Int. Ed. 2019, 58, 3421-3425.
(74) Nitrosyl Linkage Isomers: NO Coupling to N2O at a Mononuclear Site
Kundu, S.; Phu, P. N.; Ghosh, P.; Kozimor, S. A.; Bertke, J. A.; Stieber, S. C. E.*; Warren, T. H.*
J. Am. Chem. Soc. 2019, 141, 1415-1419.
2017
(73) Three-Coordinate Copper(II) Aryls: Key Intermediates in C–O Bond Formation
Kundu, S.; Greene, C.; Williams, K. D.; Salvador, T. K.; Bertke, J. A.; Cundari, T. R.*; Warren, T. H.*
J. Am. Chem. Soc., 2017, 139, 9112-9115.
(72) Elusive Terminal Copper Arylnitrene Intermediates
Bakhoda, A.; Jiang, Q.; Bertke, J. A.; Cundari, T. R.*; Warren, T. H.*
Angew. Chem. Int. Ed., 2017, 56, 6426-6430.
(71) Copper(II) Activation of Nitrite: Nitrosation of Nucleophiles and Generation of NO by Thiols
Kundu, S.*; Kim, W. Y.; Bertke, J. A.; Warren, T. H.*
J. Am. Chem. Soc., 2017, 139, 1045-1048.
(JACS Article Spotlight)
(70) Nitric oxide release via oxygen atom transfer from nitrite at copper(II)
Sakhaei, Z.; Kundu, S.; Donnelly, J. M.; Bertke, J. A.; Kim, W. Y.; Warren, T. H.*
Chem. Commun., 2017, 53, 549-552.
(69) The Chemistry of a Non-Interacting Vicinal Frustrated Phosphane/Borane Lewis Pair
Elmer, L-M.; Kehr, G.; Daniliuc, C. G.; Siedow, M.; Eckert, H.; Tesch, M.; Studer, A.; Williams, K.; Warren, T. H.; Erker, G.* Chem. Eur. J., 2017, 23, 6056-6068.
2016
(68) Copper Catalyzed sp3 C-H Etherification with Acyl Protected Phenols
Salvador, T. K.; Arnett, C. H.; Kundu, S.; Sapiezynski, N. G.; Bertke, J. A..; Boroujeni, M. R.; Warren, T. H.*
J. Am. Chem. Soc., 2016, 138, 16580-16583.
(67) A Frustrated and Confused Lewis Pair
McQuilken, A. C.; Dao, Q. M.; Cardenas, A. J. P.; Bertke, J. A.; Grimme, S.*; Warren, T. H.*
Angew. Chem. Int. Ed., 2016, 55, 14335-14339.
(66) Redox Noninnocence of Nitrosobenzene at Nickel
Kundu, S.*; Stieber, S. C. E.*; Ferrier, M. G.; Kozimor, S. A.; Bertke, J. A.; Warren, T. H.*
Angew. Chem. Int. Ed., 2016, 55, 10321-10325.
(65) A Dinitrogen Dicopper(I) Complex via a Mixed-Valence Dicopper Hydride
Zhang, S.; Fallah, H.; Gardner, E. J.; Kundu, S.; Bertke, J. A.; Cundari, T. R.*; Warren, T. H.*
Angew. Chem. Int. Ed., 2016, 55, 9927-9931.
(Hot Paper)
Wang, L.; Samigullin, K.; Wagner, M.; McQuilken, A. C.; Warren, T. H.; Daniliuc, C. G.; Kehr, G.; Erker, G.*
Chem. Eur. J., 2016, 22, 11015-11021.
(63) A Motif for Reversible Nitric Oxide Interactions in Metalloenzymes
Zhang, S.; Melzer M. M.; Nermin Sen, S.; Çelebi-Ölçüm, N.*; Warren, T. H.*
Nat. Chem., 2016, 8, 663-669. Highlighted in a Nature Chemistry Focus, Editorial and News & Views.
(62) FLPNO Nitroxide Radical Formation by a 1,1-Carboboration Route
Liedtke, R.; Eller, C.; Daniliuc, C. G.; Williams, K.; Warren, T. H.: Tesche, M.; Studer, A.; Kehr, G.; Erker, G* Organometallics, 2016, 35, 55-61.
(61) Frustrated Lewis Pair Chemistry Derived from Bulky Allenyl and Propargyl Phosphanes
Rosorius, C.; Möricke, J.; Wibbeling, B.; McQuilken, A. C.; Warren, T. H.; Daniliuc, C. G.; Kehr, G.; Erker, G.*
Chem. Eur. J., 2016, 22,1103-1113.
(60) Cooperative 1,1-addition reactions of vicinal phosphane/borane frustrated Lewis pairs
Cardenas, A. J. P.; Hasegawa, Y.; Kehr, G.; Warren, T. H.*; Erker, G.*
Coord. Chem. Rev. 2016, 306, 468-482.
2015
(59) Re-evaluating the Cu K pre-edge XAS transition in complexes with covalent metal-ligand interactions.
Tomson, N. C.*; Williams, K. D.; Dai, X.; Sproules, S.; DeBeer, S.; Warren, T. H.*; Wieghardt, K.*
Chem. Sci. 2015, 6, 2474-2487.
(58) P/B Ketene Adduct Formation from Acyl Chlorides at a Vicinal Phosphane/Borane Frustrated Lewis Pair. Frömel, S.; Radermacher, G.; Wibbeling, B.; Daniliuc, C. G.; Warren, T. H.;* Kehr, G.; Erker, G.*
Isr. J. Chem. 2015, 55, 210-215.
2014
(57) Copper(II) Anilides in sp3 C-H Amination. Jang, E. S.; McMullin, C. L.; Käß, M.; Meyer, K.*; Cundari, T. R.*; Warren, T. H.*
J. Am. Chem. Soc. 2014, 136, 10930–10940.
(56) Frustrated Lewis Pair Modification by 1,1-Carboboration: Disclosure of a Phosphine Oxide Triggered Nitrogen Monoxide Addition to an Intramolecular P/B Frustrated Lewis Pair.
Liedtke, R.; Scheidt, F.; Ren, J.; Schirmer, B.; Cardenas, A. J.; Daniliuc, C. G.; Eckert, H.; Warren, T. H.; Grimme, S.; Kehr, G.; Erker, G.*
J. Am. Chem. Soc. 2014, 136, 9014–9027.
(55) Conversion of Nitrite to Nitric Oxide at Zinc via S-Nitrosothiols.
Cardenas, A. J.; Abelman, R.; Warren, T. H.
Chem. Commun. 2014, 50, 168–170.
2013
(54) Copper(I) Nitrosyls from Reaction of copper(II) Thiolates with S-Nitrosothiols: Mechanism of NO Release from RSNOs at Cu. Zhang, S.; Çelebi-Ölçüm, N.*; Melzer, M. M.; Houk, K. N.; Warren, T. H.*
J. Am. Chem. Soc. 2013, 135, 16746–16749.
(53) Copper C-nitroso Compounds: Activation of Hydroxylamines and NO Reactivity.
Williams, K. D.; Cardenas, A. J. P.; Oliva, J. D.; Warren, T. H.*
Eur. J. Inorg. Chem. 2013, 3812-3816.
(52) Mechanistic Insights into C-H Amination via Dicopper Nitrenes.
Aguila, M. J.; Badiei, Y. M.; Warren, T. H.*
J. Am. Chem. Soc. 2013, 135, 9399–9406.
(51) Noninteracting, Vicinal Frustrated P/B-Lewis Pair at the Norbornane Framework: Synthesis, Characterization, and Reactions. Sajid, M.; Kehr, G.; Wiegand, T.; Eckert, H.; Schwickert, C.; Pöttgen, R.; Cardenas, A. J.; Warren, T. H.; Fröhlich, R.; Daniliuc, C. G.; Erker, G.
J. Am. Chem. Soc. 2013, 135, 8882–8895.
(50) β-Diketiminato Nickel Imides in Catalytic Nitrene Transfer to Isocyanides.
Wiese, S.; Aguila, M. J. B.; Kogut, E.; Warren, T. H.*
Organometallics, 2013, 32, 2300-2308.
(49) Radical Frustrated Lewis Pairs. Warren, T. H.; Erker, G. Top. Curr. Chem. 2013, 334, 219–238.
(48) Three coordinate models for the binuclear CuA electron- transfer site. Zhang, S.; Warren, T. H. Chem Sci. 2013, 4, 1786-1792.
2012
(47) Copper-Catalyzed sp3 C–H Amination. Gephart, R.; Warren, T. Organometallics 2012, 31, 7728-7752.
(46) Reaction of Cu(I) with Dialkyl Peroxides: Cu(II)-Alkoxides, Alkoxy Radicals, and Catalytic C-H Etherification. Gephart, R. T.; McMullin, C. L.; Sapiezynski, N. G.; Jang, E. S.; Aguila, M. J.; Cundari, T. R.; Warren, T. H. J. Am. Chem. Soc. 2012, 134, 17350–17353.
(45) A copper(II) Thiolate from Reductive Cleavage of an S-Nitrosothiol. Melzer, M. M.; Mossin, S.; Cardenas, A. J.; Williams, K. D.; Zhang, S.; Meyer, K.; Warren, T. H. Inorg. Chem. 2012, 51, 8658–8660.
(44) C-H Functionalization Reactivity of a Nickel-Imide. Wiese, S.; McAfee, J. L.; Pahls, D. R.; McMullin, C. L.; Cundari, T. R.; Warren, T. H. J. Am. Chem. Soc. 2012, 134, 10114–10121.
(43) Catalytic C-H Amination with Aromatic Amines. Gephart, R. T.; Huang, D. L.; Aguila, M. J.; Schmidt, G.; Shahu, A.; Warren, T. H. Angew. Chem. Int. Ed. 2012, 51, 6488–6492.
(42) N,N-Addition of Frustrated Lewis Pairs to Nitric Oxide: An Easy Entry to a Unique Family of Aminoxyl Radicals. Sajid, M.; Stute, A.; Cardenas, A. J.; Culotta, B. J.; Hepperle, J. A.; Warren, T. H.; Schirmer, B.; Grimme, S.; Studer, A.; Daniliuc, C. G.; Fröhlich, R.; Petersen, J. L.; Kehr, G.; Erker, G. J. Am. Chem. Soc. 2012, 134, 10156–10168.
2011
(41) Synthesis and Structure-Activity Evaluation of Isatin-β-Thiosemicarbazones with Improved Selective Activity toward Multidrug-Resistant Cells Expressing P-Glycoprotein. Hall, M. D.; Brimacombe, K. R.; Varonka, M. S.; Pluchino, K. M.; Monda, J. K.; Li, J.; Walsh, M. J.; Boxer, M. B.; Warren, T. H.; Fales, H. M.; Gottesman, M. M. J. Med. Chem. 2011, 54, 5878–5889.
(40) Capture of NO by a Frustrated Lewis Pair: A New Type of Persistent N-Oxyl Radical. Cardenas, A. J.; Culotta, B. J.; Warren, T. H.; Grimme, S.; Stute, A.; Fröhlich, R.; Kehr, G.; Erker, G. Angew. Chem. Int. Ed. 2011, 50, 7567–7571.
2010
(39) Catalytic C-H Amination with Unactivated Amines through copper(II) Amides. Wiese, S.; Badiei, Y. M.; Gephart, R. T.; Mossin, S.; Varonka, M. S.; Melzer, M. M.; Meyer, K.; Cundari, T. R.; Warren, T. H. Angew.Chem. Int. Ed. 2010, 49, 8850–8855.
(38) Copper 2,4-bis-(2,6-diisopropylphenylimido)pentyl chloride (LMe,iPr2CuCl). Holland, P. L.*; Melzer, M. M.; Warren, T. H.* Inorg. Synth. 2010, 35, 54-55.
(37) Bis[copper 2,4-bis-(2,4,6-trimethylphenylimido)pentyl]toluene, (LMe,Me3Cu)2(μ-η2:η2-C7H8). Badiei, Y. M.; Warren, T. H.*; Chiang, K. P.; Holland, P. L. " Inorg. Synth. 2010, 35, 50-53.
(36) Nickel 2,4-bis-(2,6-diisopropylphenylimido)pentyl chloride dimer, [LMe,iPr2Ni(μ-Cl)]2. Dugan, T. R.; Holland, P. L.*; Wiese, S.; Warren, T. H.* Inorg. Synth. 2010, 35, 48-50.
(35) β-Diketiminate Supported Nickel(II) and Nickel(I) Complexes of LMe,Me3(LMe,Me3= 2,4-bis(mesitylimido)pentyl). Melzer, M. M.; Kogut, E.; Varonka, M. S.; Wiese, S.; Warren, T. H.*; Rocks, S. S.; Holland, P. L. Inorg. Synth. 2010, 35, 45-48.
(34) β-Diketiminate Supported Manganese and Zinc Complexes. Roesky, H. W.;* Varonka, M. S.; Warren, T. H.* Inorg. Synth. 2010, 35, 34-38.
(33) β-Diketiminate Supported Vanadium and Chromium Chloride Complexes. Puttnual, C.; MacAdams, L. A.; Theopold, K. H.*; Badiei, Y. M.; Warren, T. H.* Inorg. Synth. 2010, 35, 30-35.
(32) β-Diketiminate Precursors HLMe,Me3 and TlLMe,Me3 (LMe,Me3 = 2,4-Bis- (2,6-mesitylimido)pentyl). Varonka, M. S.; Warren, T.H.*; Dugan, T. R.; Cowley, R. E.; Holland, P. L. Inorg. Synth. 2010, 35, 4-8.
(31) Complexes of Bulky β-Diketiminate Ligands. Introduction. Mindiola, D. J.*; Holland, P. L.*; Warren, T. H.* Inorg. Synth. 2010, 35, 1-4.
(30) Three-Coordinate copper(II) Amide from Reductive Cleavage of a Nitrosamine. Melzer, M. M.; Mossin, S.; Dai, X.; Bartell, A. M.; Kapoor, P.; Meyer, K.; Warren, T. H. Angew. Chem. Int. Ed. 2010, 49, 904–907.
(29) Three Coordinate N-heterocyclic Carbene Nickel Nitrosyl Complexes. Varonka, M. S.; Warren, T. H.* Organometallics 2010, 29, 717-720.
2009
(28) Nitric Oxide Oxidatively Nitrosylates Ni(I) and Cu(I) C-Organonitroso Adducts. Wiese, S.; Kapoor, P.; Williams, K. D.; Warren, T. H. J. Am. Chem. Soc. 2009, 131, 18105–18111.
(27) Reversible RS-NO Bond Cleavage and Formation at copper(I) Thiolates. Melzer, M. M.; Li, E.; Warren, T. H. Chem. Commun. 2009, 5847–5849.
(26) S-Nitrosothiol and Nitric Oxide Reactivity at Zinc Thiolates. Varonka, M. S.; Warren, T. H. Inorg. Chem. 2009, 48, 5605–5607.
2008
(25) Copper-Nitrene Complexes in Catalytic C-H Amination. Badiei, Y. M.; Dinescu, A.; Dai, X.; Palomino, R. M.; Heinemann, F. W.; Cundari, T. R.; Warren, T. H. Angew. Chem. Int. Ed. 2008, 47, 9961–9964.
(24) Reductive Cleavage of O-, S-, and N-Organonitroso Compounds by nickel(I) β-Diketiminates. Melzer, M. M.; Jarchow-Choy, S.; Kogut, E.; Warren, T. H. Inorg. Chem. 2008, 47, 10187–10189.
2007
(23) Preface - Insertion chemistry of the metal-carbon bond: A tribute to Gerhard Erker. Warren, T. H.* J. Organometal. Chem. 2007, 692, xvii-xix.
(22) Solid-State (63)Cu and (65)Cu NMR Spectroscopy of Inorganic and Organometallic copper(I) Complexes. Tang, J. A.; Ellis, B. D.; Warren, T. H.; Hanna, J. V.; Macdonald, C. L.; Schurko, R. W. J. Am. Chem. Soc. 2007, 129, 13049–13065.
(21) S-Nitrosothiol and Nitric Oxide Reactivity at β-Diketiminato Zinc-Thiolates. Varonka, M. S.; Warren, T. H.* Inorg. Chim. Acta 2007, 360, 317-328. Special invited contribution to their Top 40 Under 40 issue – The Next Generation
2006
(20) Transient Terminal Cu-Nitrene Intermediates from Discrete Dicopper Nitrenes. Badiei, Y. M.; Krishnaswamy, A.; Melzer, M. M.; Warren, T. H. J. Am. Chem. Soc. 2006, 128, 15056–15057.
2005
(19) A Terminal Ni(III)-Imide with Diverse Reactivity Pathways. Kogut, E.; Wiencko, H. L.; Zhang, L.; Cordeau, D. E.; Warren, T. H. J. Am. Chem. Soc. 2005, 127, 11248–11249.
(18) Electronic structure and electrophilic reactivity of discrete copper diphenylcarbenes. Badiei, Y. M.; Warren, T. H. Journal of Organometallic Chemistry 2005, 690, 5989–6000.
2004
(17) Non-linear optically active zinc and cadmium p-pyridinecarboxylate coordination networks. Ayyappan, P.; Sirokman, G.; Evans, O. R.; Warren, T. H. and Lin, W.* Inorg. Chim. Acta 2004, 37, 3999-4004.
(16) Cu(I) β-Diketiminates for Alkene Aziridination: Reversible Cu-Arene Binding and Catalytic Nitrene Transfer from PhI=NTs. Amisial, L. D.; Dai, X.; Kinney, R. A.; Krishnaswamy, A.; Warren, T. H. Inorg. Chem. 2004, 43, 6537–6539.
(15) Structure and Dynamics of Neutral β-H Agostic Nickel Alkyls: A Combined Experimental and Theoretical Study. Kogut, E.; Zeller, A.; Warren, T. H.; Strassner, T. J. Am. Chem. Soc. 2004, 126, 11984–11994.
(14) Discrete Bridging and Terminal Copper Carbenes in Copper-Catalyzed Cyclopropanation. Dai, X.; Warren, T. H. J. Am. Chem. Soc. 2004, 126, 10085–10094.
(13) [Me2NN]Co(η6-Toluene): O=O, N=N, and O=N Bond Cleavage Provides β-Diketiminato Cobalt μ-Oxo and Imido Complexes. Dai, X.; Kapoor, P.; Warren, T. H. J. Am. Chem. Soc. 2004, 126, 4798–4799.
2003
(12) Three-coordinate β-diketiminato nickel nitrosyl complexes from nickel (I)-lutidine and nickel (II)-alkyl precursors. Puiu, S. C.; Warren, T. H. Organometallics 2003, 22, 3974-3976.
(11) Neutral β-diketiminato nickel (II) monoalkyl complexes. Wiencko, H. L.; Kogut, E.; Warren, T. H. Inorg. Chim. Acta 2003. 345, 199-208.
2001
(10) New Open Frameworks Based on Metal Pyridylphosphonates. Ayyappan, P.; Evans, O. R.; Foxman, B. M.; Wheeler, K. A.; Warren, T. H.; Lin, W. Inorg. Chem. 2001, 40, 5954-5961.
(9) Dioxygen Activation by a β-Diketiminato Cu(I) Ethylene Complex. Dai, X.; Warren, T.H.* Chem. Commun. 2001,
1993-2000
Publications from Postdoctoral, Graduate, and Undergraduate Studies
(8) Formation and Structural Properties of Salicylaldiminato Complexes of Zirconium and Titanium. Strauch, J; Warren, TH; Erker, G; Fröhlich, R.; Saarenketo, P. Inorg. Chim. Acta. 2000, 810-821.
(7) 1, 3-Doubly Bridged Group 4 Metallocenes by Intramolecular Reductive Coupling of Pendant Olefins. Warren, T. H.; Erker, G.; Fröhlich, R.; Wibbeling, B. Organometallics 2000. 19, 127-134.
(6) a-Hydrogen Migration Reactions in Tungsten(VI) Cyclopentadienyl Alkylidyne Complexes. Warren, T. H.; Schrock, R. R.*; Davis, W. M. J. Organomet. Chem.1998, 569, 125-137.
(5) Neutral and Cationic Group 4 Complexes Containing Bis (borylamide) Ligands,[R2BNCH2CH2NBR2]2-(R= 2, 4, 6-I-Pr3C6H2, M= Zr; R= Cyclohexyl, M= Ti, Zr, Hf). Warren, T. H.; Schrock, R. R.; Davis, W. M. Organometallics 1998, 17, 308-321.
(4) Synthesis of Group 4 Organometallic Complexes That Contain the Bis (borylamide) Ligand [Mes2BNCH2CH2NBMes2]-2. Warren, T. H.; Schrock, R. R.; Davis, W. M. Organometallics 1996, 15, 562-569.
(3) Iron(0) Arene and Iron(II) Hydride Complexes from the Hydrogenation or Thermolysis of High-spin Iron(II) Alkyls. Hermes, A. R.; Warren, T. H.‡; Girolami, G. S.* J. Chem. Soc., Dalton Trans.1995, 301-305.
(2) Ligand Electronic Effects in Asymmetric Catalysis: Enhanced Enantioselectivity in the Asymmetric Hydrocyanation of Vinylarenes. Casalnuovo, A. L.; Rajan Babu, T. V.; Ayers, T. A.; Warren, T. H. J. Am. Chem. Soc. 1994, 116, 9869–9882.
(1) Surface-Selective Deposition of Palladium and Silver Films from Metal-Organic Precursors: A Novel Metal-Organic Chemical Vapor Deposition Redox Transmetalation Process. Lin, W.; Warren, T. H.; Nuzzo, R. G.; Girolami, G. S. J. Am. Chem. Soc.1993, 115, 11644-11645.
