2016   2015    2014    2013    2012    2011    2010    2009    2008    2007    2006    2005    2004    2003    2001


(73) Three-Coordinate Copper(II) Aryls: Key Intermediates in C–O Bond Formation

Kundu, S.; Greene, C.; Williams, K. D.; Salvador, T. K.; Bertke, J. A.; Cundari, T. R.; Warren, T. H. J. Am. Chem. Soc., 2017 (Article ASAP). doi: 10.1021/jacs.7b04046

(72) Elusive Terminal Copper Arylnitrene Intermediates

Bakhoda, A.; Jiang, Q.; Bertke, J. A.; Cundari, T. R.; Warren, T. H. Angew. Chem. Int. Ed., 2017 (Early View). doi: 10.1002/anie.201611275

(71)   Copper(II) Activation of Nitrite: Nitrosation of Nucleophiles and Generation of NO by Thiols

Kundu, S.; Kim, W. Y.; Bertke, J. A.; Warren, T. H. J. Am. Chem. Soc. 2017139, 1045-1048. doi:10.1021/jacs.6b11332 (JACS Article Spotlight)


(70)   Nitric oxide release via oxygen atom transfer from nitrite at copper(II)

Sakhaei, Z.; Kundu, S.; Donnelly, J. M.; Bertke, J. A.; Kim, W. Y.; Warren, T. H. Chem. Commun., 201753, 549-552. doi: 10.1039/C6CC08745K 

(69)   The Chemistry of a Non-Interacting Vicinal Frustrated Phosphane/Borane Lewis Pair

Elmer, L-M.; Kehr, G.; Daniliuc, C. G.; Siedow, M.; Eckert, H.; Tesch, M.; Studer, A.; Williams, K.; Warren, T. H.; Erker, G. Chem. Eur. J.201723, 6056-68. doi: 10.1002/chem.201603954



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(68)   Copper Catalyzed sp3 C-H Etherification with Acyl Protected Phenols

Salvador, T. K.; Arnett, C. H.; Kundu, S.; Sapiezynski, N. G.; Bertke, J. A..; Boroujeni, M. R.; Warren, T. H. J. Am. Chem. Soc., 2016138, 16580-16583. doi: 10.1021/jacs.6b09057



(67)   A Frustrated and Confused Lewis Pair

McQuilken, A. C.; Dao, Q. M.; Cardenas, A. J. P.; Bertke, J. A.; Grimme, S.; Warren, T. H. Angew. Chem. Int. Ed., 2016, 55, 14335-14339. doi: 10.1002/anie.201608968


(66) Redox Noninnocence of Nitrosobenzene at Nickel

Kundu, S.; Stieber, S. C. E.; Ferrier, M. G.; Koximor, S. A.; Bertke, J. A.; Warren, T. H. Angew. Chem. Int. Ed., 201655, 10321-10325. doi:10.1002/anie.201605026


(65)   A Dinitrogen Dicopper(I) Complex via a Mixed-Valence Dicopper Hydride 

Zhang, S.; Fallah, H.; Gardner, E. J.; Kundu, S.; Bertke, J. A.; Cundari, T. R.; Warren, T. H. Angew. Chem. Int. Ed., 2016, 55, 9927-9931. doi:10.1002/anie.201603970  (Hot Paper)

Angewandte CuN2 paper TOC

(64)   An Ethylene-Bridged Phosphane/Borane Frustrated Lewis Pair Featuring the -B(Fxyl)2 Lewis Acid Component

Wang, L.; Samigullin, K.; Wagner, M.; McQuilken, A. C.; Warren, T. H.; Daniliuc, C. G.; Kehr, G. Chem. Eur. J., 201622, 11015-11021. doi:10.1002/chem.201601583


(63)   A Motif for Reversible Nitric Oxide Interactions in Metalloenzymes

Zhang, S.; Melzer M. M.; Nermin Sen, S.; Çelebi-Ölçüm, N.; Warren, T. H. Nat. Chem., 20168, 663-669. doi:10.1038/nchem.2502



(62)  FLPNO Nitroxide Radical Formation by a 1,1-Carboboration Route

Liedtke, R.; Eller, C.; Daniliuc, C. G.; Williams, K.; Warren, T. H.: Tesche, M.; Studer, A.; Kehr, G.; Erker, G. Organometallics, 201635, 55-61. doi: 10.1021/acs.organomet.5b00886




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(61)  Frustrated Lewis Pair Chemistry Derived from Bulky Allenyl and Propargyl Phosphanes. Rosorius, C.; Möricke, J.; Wibbeling, B.; McQuilken, A. C.; Warren, T. H.; Daniliuc, C. G.; Kehr, G.; Erker, G.* Chem. Eur. J., 2015. doi: 10.1002/chem.201502493


(60)  Cooperative 1,1-addition reactions of vicinal phosphane/borane frustrated Lewis pairs. Cardenas, A. J. P.; Hasegawa, Y.; Kehr, G.; Warren, T. H.; Erker, G. Coord. Chem. Rev. 2015 doi: 10.1016/j.ccr.2015.01.006.


(59)  Re-evaluating the Cu K pre-edge XAS transition in complexes with covalent metal-ligand interactions. Tomson, N. C.; Williams, K. D.; Dai, X.; Sproules, S.; DeBeer, S.; Warren, T. H.; Wieghardt, K. Chem. Sci. 2015, 6, 2474-2487.


(58)  P/B Ketene Adduct Formation from Acyl Chlorides at a Vicinal Phosphane/Borane Frustrated Lewis Pair. Frömel, S.; Radermacher, G.; Wibbeling, B.; Daniliuc, C. G.; Warren, T. H.;* Kehr, G.; Erker, G.* Isr. J. Chem. 2015, 55, 210-215.




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(57)  Copper(II) Anilides in spC-H Amination. Jang, E. S.; McMullin, C. L.; Käß, M.; Meyer, K.; Cundari, T. R.; Warren, T. H. J. Am. Chem. Soc. 2014136, 10930–10940.

(56)  Frustrated Lewis Pair Modification by 1,1-Carboboration: Disclosure of a Phosphine Oxide Triggered Nitrogen Monoxide Addition to an Intramolecular P/B Frustrated Lewis Pair. Liedtke, R.; Scheidt, F.; Ren, J.; Schirmer, B.; Cardenas, A. J.; Daniliuc, C. G.; Eckert, H.; Warren, T. H.; Grimme, S.; Kehr, G.; Erker, G. J. Am. Chem. Soc. 2014136, 9014–9027.

(55)  Conversion of Nitrite to Nitric Oxide at Zinc via S-Nitrosothiols Cardenas, A. J.; Abelman, R.; Warren, T. H. Chem. Commun. 201450, 168–170.


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(54)  Copper(I) Nitrosyls from Reaction of copper(II) Thiolates with S-Nitrosothiols: Mechanism of NO Release from RSNOs at CuZhang, S.; Çelebi-Ölçüm, N.; Melzer, M. M.; Houk, K. N.; Warren, T. H. J. Am. Chem. Soc.2013135, 16746–16749.

(53)  Copper C-nitroso Compounds: Activation of Hydroxylamines and NO Reactivity. Williams, K. D.; Cardenas, A. J. P.; Oliva, J. D.; Warren, T. H.* Eur. J. Inorg. Chem. 2013, 3812-3816.


(52)  Mechanistic Insights into C-H Amination via Dicopper Nitrenes. Aguila, M. J.; Badiei, Y. M.; Warren, T. H. J. Am. Chem. Soc. 2013135, 9399–9406.

(51)  Noninteracting, Vicinal Frustrated P/B-Lewis Pair at the Norbornane Framework: Synthesis, Characterization, and Reactions. Sajid, M.; Kehr, G.; Wiegand, T.; Eckert, H.; Schwickert, C.; Pöttgen, R.; Cardenas, A. J.; Warren, T. H.; Fröhlich, R.; Daniliuc, C. G.; Erker, G. J. Am. Chem. Soc. 2013135, 8882–8895.

(50)  β-Diketiminato Nickel Imides in Catalytic Nitrene Transfer to Isocyanides. Wiese, S.; Aguila, M. J. B.; Kogut, E.; Warren, T. H.* Organometallics 2013, 32, 2300-2308.

(49)  Radical Frustrated Lewis Pairs. Warren, T. H.; Erker, G. Top. Curr. Chem. 2013334, 219–238.

(48)  Three coordinate models for the binuclear CuA electron- transfer site. Zhang, S.; Warren, T. H. Chem Sci. 2013, 4, 1786-1792.


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(47)  Copper-Catalyzed sp3 C–H Amination. Gephart, R.; Warren, T. Organometallics 201231, 7728-7752.

(46)  Reaction of Cu(I) with Dialkyl Peroxides: Cu(II)-Alkoxides, Alkoxy Radicals, and Catalytic C-H Etherification. Gephart, R. T.; McMullin, C. L.; Sapiezynski, N. G.; Jang, E. S.; Aguila, M. J.; Cundari, T. R.; Warren, T. H. J. Am. Chem. Soc. 2012134, 17350–17353.

(45)  A copper(II) Thiolate from Reductive Cleavage of an S-Nitrosothiol. Melzer, M. M.; Mossin, S.; Cardenas, A. J.; Williams, K. D.; Zhang, S.; Meyer, K.; Warren, T. H. Inorg. Chem. 201251, 8658–8660.

(44)  C-H Functionalization Reactivity of a Nickel-Imide. Wiese, S.; McAfee, J. L.; Pahls, D. R.; McMullin, C. L.; Cundari, T. R.; Warren, T. H. J. Am. Chem. Soc. 2012134, 10114–10121.

(43)  Catalytic C-H Amination with Aromatic Amines. Gephart, R. T.; Huang, D. L.; Aguila, M. J.; Schmidt, G.; Shahu, A.; Warren, T. H. AngewChem. Int. Ed. 201251, 6488–6492.


(42)  N,N-Addition of Frustrated Lewis Pairs to Nitric Oxide: An Easy Entry to a Unique Family of Aminoxyl Radicals. Sajid, M.; Stute, A.; Cardenas, A. J.; Culotta, B. J.; Hepperle, J. A.; Warren, T. H.; Schirmer, B.; Grimme, S.; Studer, A.; Daniliuc, C. G.; Fröhlich, R.; Petersen, J. L.; Kehr, G.; Erker, G. J. Am. Chem. Soc. 2012134, 10156–10168.


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(41)  Synthesis and Structure-Activity Evaluation of Isatin-β-Thiosemicarbazones with Improved Selective Activity toward Multidrug-Resistant Cells Expressing P-GlycoproteinHall, M. D.; Brimacombe, K. R.; Varonka, M. S.; Pluchino, K. M.; Monda, J. K.; Li, J.; Walsh, M. J.; Boxer, M. B.; Warren, T. H.; Fales, H. M.; Gottesman, M. M. J. Med. Chem. 201154, 5878–5889.
untitled(40) Capture of NO by a Frustrated Lewis Pair: A New Type of Persistent N-Oxyl RadicalCardenas, A. J.; Culotta, B. J.; Warren, T. H.; Grimme, S.; Stute, A.; Fröhlich, R.; Kehr, G.; Erker, G. Angew. Chem. Int. Ed. 201150, 7567–7571.



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(39)  Catalytic C-H Amination with Unactivated Amines through copper(II) Amides. Wiese, S.; Badiei, Y. M.; Gephart, R. T.; Mossin, S.; Varonka, M. S.; Melzer, M. M.; Meyer, K.; Cundari, T. R.; Warren, T. H. Angew. Chem. Int. Ed. 201049, 8850–8855.

(38)  Copper 2,4-bis-(2,6-diisopropylphenylimido)pentyl chloride (LMe,iPr2CuCl). Holland, P. L.*; Melzer, M. M.; Warren, T. H.* Inorg. Synth. 2010, 35, 54-55.

(37)  Bis[copper 2,4-bis-(2,4,6-trimethylphenylimido)pentyl]toluene, (LMe,Me3Cu)2(μ-η22-C7H8). Badiei, Y. M.; Warren, T. H.*; Chiang, K. P.; Holland, P. L. " Inorg. Synth. 2010, 35, 50-53.

(36)  Nickel 2,4-bis-(2,6-diisopropylphenylimido)pentyl chloride dimer, [LMe,iPr2Ni(μ-Cl)]2. Dugan, T. R.; Holland, P. L.*; Wiese, S.; Warren, T. H.* Inorg. Synth. 2010, 35, 48-50.

(35)  β-Diketiminate Supported Nickel(II) and Nickel(I) Complexes of LMe,Me3 (LMe,Me3 = 2,4-bis(mesitylimido)pentyl). Melzer, M. M.; Kogut, E.; Varonka, M. S.; Wiese, S.; Warren, T. H.*; Rocks, S. S.; Holland, P. L. Inorg. Synth. 2010, 35, 45-48.

(34)  β-Diketiminate Supported Manganese and Zinc Complexes. Roesky, H. W.;* Varonka, M. S.; Warren, T. H.* Inorg. Synth. 2010, 35, 34-38.

(33)  β-Diketiminate Supported Vanadium and Chromium Chloride Complexes. Puttnual, C.; MacAdams, L. A.; Theopold, K. H.*; Badiei, Y. M.; Warren, T. H.* Inorg. Synth. 2010, 35, 30-35.

(32)  β-Diketiminate Precursors HLMe,Me3 and TlLMe,Me3 (LMe,Me3 = 2,4-Bis- (2,6-mesitylimido)pentyl). Varonka, M. S.; Warren, T.H.*; Dugan, T. R.; Cowley, R. E.; Holland, P. L. Inorg. Synth. 2010, 35, 4-8.

(31)  Complexes of Bulky β-Diketiminate Ligands. Introduction. Mindiola, D. J.*; Holland, P. L.*; Warren, T. H.* Inorg. Synth. 2010, 35, 1-4.

(30)  Three-Coordinate copper(II) Amide from Reductive Cleavage of a Nitrosamine. Melzer, M. M.; Mossin, S.; Dai, X.; Bartell, A. M.; Kapoor, P.; Meyer, K.; Warren, T. H. A Angew. Chem. Int. Ed. 201049, 904–907.

(29)  Three Coordinate N-heterocyclic Carbene Nickel Nitrosyl Complexes. Varonka, M. S.; Warren, T. H.* Organometallics 2010, 29, 717-720.


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(28)  Nitric Oxide Oxidatively Nitrosylates Ni(I) and Cu(I) C-Organonitroso Adducts. Wiese, S.; Kapoor, P.; Williams, K. D.; Warren, T. H. J. Am. Chem. Soc. 2009131, 18105–18111.
Microsoft Word - $ASQ623434_File000004_5963498.doc

(27)  Reversible RS-NO Bond Cleavage and Formation at copper(I) Thiolates. Melzer, M. M.; Li, E.; Warren, T. H. Chem. Commun. 2009, 5847–5849.

(26)  S-Nitrosothiol and Nitric Oxide Reactivity at Zinc Thiolates. Varonka, M. S.; Warren, T. H. Inorg. Chem. 200948, 5605–5607.
Microsoft Word - $ASQ554934_File000002_4914379.doc


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(25)  Copper-Nitrene Complexes in Catalytic C-H Amination. Badiei, Y. M.; Dinescu, A.; Dai, X.; Palomino, R. M.; Heinemann, F. W.; Cundari, T. R.; Warren, T. H. Angew. Chem. Int. Ed. 200847, 9961–9964.

(24)  Reductive Cleavage of O-, S-, and N-Organonitroso Compounds by nickel(I) β-Diketiminates. Melzer, M. M.; Jarchow-Choy, S.; Kogut, E.; Warren, T. H. Inorg. Chem. 200847, 10187–10189.Microsoft Word - Warren-TOC.doc


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(23)  Preface - Insertion chemistry of the metal-carbon bond: A tribute to Gerhard Erker. Warren, T. H.* J. Organometal. Chem. 2007, 692, xvii-xix.

(22)  Solid-State (63)Cu and (65)Cu NMR Spectroscopy of Inorganic and Organometallic copper(I) Complexes. Tang, J. A.; Ellis, B. D.; Warren, T. H.; Hanna, J. V.; Macdonald, C. L.; Schurko, R. W. J. Am. Chem. Soc. 2007129, 13049–13065.

(21)  S-Nitrosothiol and Nitric Oxide Reactivity at β-Diketiminato Zinc-Thiolates. Varonka, M. S.; Warren, T. H.* Inorg. Chim. Acta 2007, 360, 317-328. Special invited contribution to their Top 40 Under 40 issue – The Next Generation


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(20)  Transient Terminal Cu-Nitrene Intermediates from Discrete Dicopper Nitrenes. Badiei, Y. M.; Krishnaswamy, A.; Melzer, M. M.; Warren, T. H. J. Am. Chem. Soc. 2006128, 15056–15057.


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(19)  A Terminal Ni(III)-Imide with Diverse Reactivity Pathways. Kogut, E.; Wiencko, H. L.; Zhang, L.; Cordeau, D. E.; Warren, T. H. J. Am. Chem. Soc. 2005127, 11248–11249.

(18)  Electronic structure and electrophilic reactivity of discrete copper diphenylcarbenes. Badiei, Y. M.; Warren, T. H. Journal of Organometallic Chemistry 2005690, 5989–6000.


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(17)  Non-linear optically active zinc and cadmium p-pyridinecarboxylate coordination networks. Ayyappan, P.; Sirokman, G.; Evans, O. R.; Warren, T. H. and Lin, W.* Inorg. Chim. Acta 2004, 37, 3999-4004.

(16)  Cu(I) β-Diketiminates for Alkene Aziridination: Reversible Cu-Arene Binding and Catalytic Nitrene Transfer from PhI=NTs. Amisial, L. D.; Dai, X.; Kinney, R. A.; Krishnaswamy, A.; Warren, T. H. Inorg. Chem. 200443, 6537–6539.

(15)  Structure and Dynamics of Neutral β-H Agostic Nickel Alkyls: A Combined Experimental and Theoretical Study. Kogut, E.; Zeller, A.; Warren, T. H.; Strassner, T. J. Am. Chem. Soc. 2004126, 11984–11994.

(14)  Discrete Bridging and Terminal Copper Carbenes in Copper-Catalyzed Cyclopropanation. Dai, X.; Warren, T. H. J. Am. Chem. Soc. 2004126, 10085–10094.

(13)  [Me2NN]Co(η6-Toluene): O=O, N=N, and O=N Bond Cleavage Provides β-Diketiminato Cobalt μ-Oxo and Imido Complexes. Dai, X.; Kapoor, P.; Warren, T. H. J. Am. Chem. Soc. 2004126, 4798–4799.


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(12)  Three-coordinate β-diketiminato nickel nitrosyl complexes from nickel (I)-lutidine and nickel (II)-alkyl precursors. Puiu, S. C.; Warren, T. H. Organometallics 2003, 22, 3974-3976.

(11)  Neutral β-diketiminato nickel (II) monoalkyl complexes. Wiencko, H. L.; Kogut, E.; Warren, T. H. Inorganica Chimica Acta. 2003. 345, 199-208.


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(10)  New Open Frameworks Based on Metal Pyridylphosphonates. Ayyappan, P.; Evans, O. R.; Foxman, B. M.; Wheeler, K. A.; Warren, T. H.; Lin, W. Inorg. Chem. 2001, 40, 5954-5961.

(9)   Dioxygen Activation by a β-Diketiminato Cu(I) Ethylene Complex. Dai, X.; Warren, T.H.* Chem. Commun. 2001, 1998-1999.


Publications from Postdoctoral, Graduate, and Undergraduate Studies

(8)   Formation and Structural Properties of Salicylaldiminato Complexes of Zirconium and Titanium. Strauch, J; Warren, TH; Erker, G; Fröhlich, R.; Saarenketo, P. Inorganica Chimica Acta2000, 810-821.

(7)   1, 3-Doubly Bridged Group 4 Metallocenes by Intramolecular Reductive Coupling of Pendant Olefins. Warren, T. H.; Erker, G.; Fröhlich, R.; Wibbeling, B. Organometallics 2000. 19, 127-134.

(6)   a-Hydrogen Migration Reactions in Tungsten(VI) Cyclopentadienyl Alkylidyne Complexes. Warren, T. H.; Schrock, R. R.*; Davis, W. M. J. Organomet. Chem. 1998, 569, 125-137.

(5)   Neutral and Cationic Group 4 Complexes Containing Bis (borylamide) Ligands,[R2BNCH2CH2NBR2]2- (R= 2, 4, 6-I-Pr3C6H2, M= Zr; R= Cyclohexyl, M= Ti, Zr, Hf). Warren, T. H.; Schrock, R. R.; Davis, W. M. Organometallics 1998, 17, 308-321.

(4)   Synthesis of Group 4 Organometallic Complexes That Contain the Bis (borylamide) Ligand [Mes2BNCH2CH2NBMes2]-2. Warren, T. H.; Schrock, R. R.; Davis, W. M. Organometallics 1996, 15, 562-569.

(3)   Iron(0) Arene and Iron(II) Hydride Complexes from the Hydrogenation or Thermolysis of High-spin Iron(II) Alkyls. Hermes, A. R.; Warren, T. H.; Girolami, G. S.* J. Chem. Soc., Dalton Trans. 1995, 301-305.

(2)   Ligand Electronic Effects in Asymmetric Catalysis: Enhanced Enantioselectivity in the Asymmetric Hydrocyanation of Vinylarenes. Casalnuovo, A. L.; RajanBabu, T. V.; Ayers, T. A.; Warren, T. H. J. Am. Chem. Soc. 1994116, 9869–9882.

(1)   Surface-Selective Deposition of Palladium and Silver Films from Metal-Organic Precursors: A Novel Metal-Organic Chemical Vapor Deposition Redox Transmetalation Process. Lin, W.; Warren, T. H.; Nuzzo, R. G.; Girolami, G. S. J. Am. Chem. Soc.1993, 115, 11644-11645.